1. 個人簡介:
姓名:餘焓
職稱:教授
簡介:餘焓博士,教授,上海交通大學應用化學博士,清華大學化學系博士後;劍橋大學化學系高級訪問學者,入選上海市海外高層次人才計劃。一直從事催化劑的研究,涉及金屬氧化物催化劑的設計與合成,精細化學品的高效催化與合成 ;環境友好的催化過程(光電熱反應條件下的多/均相催化、仿生催化和環境催化), 至今以第一/通訊作者發表SCI論文50餘篇,包括Angew. Chem. Int. Ed.J. Am. Chem. Soc.等。提出了“無機配體催化劑”的新理念,發展了金屬氧化物均相催化的新方法,産學研方面創建了産業界少有的綠色選擇性氧化反應技術中心,獲得比亞迪系等多家風投機構投資,多項催化劑成果應用于工業化。
2. 研究領域:
[1] 催化劑的設計與合成
[2] 精細化學品的高效催化與合成
[3] 環境友好的催化過程(光、電、熱條件下的多/均相催化、仿生催化和環境催化)
3 學術兼職
國家自然科學基金評審專家,擔任ACS, Wiley, RSC, Elsevier等多個出版社的學術期刊審稿人;
4 項目與榮譽
[1] 多金屬氧酸鹽催化醇的選擇性氧化體系構建及其在合成化學中的應用,國家自然科學基金(面上項目)2019-2022;
[2] 基于烷基硼為親核試劑手性亞磷酰胺Cu催化的Michael反應的研究,國家自然科學基金(青年項目) 2015-2017;
[3] 第三屆“海聚英才”全球創新創業大賽三等獎;
[4] HICOOL2023全球創新創業大賽二等獎;
[5] 2022年高等學校科學研究優秀成果獎二等獎,(排名第二);
[6] 第九屆中國海歸創業大賽優勝獎, (排名第一);
[7] 2022年上海市闵行區傑出人才(上海市闵行區委和政府);
5. 成果:
代表性論文:
[1] Han Yu*, et al.“Imparting Functionality to Nano-sized Metal-Organic Framework by Controlled Coordination of Methoxy PEG Phosphate” J. Am. Chem. Soc.2021, 143, 13557-13572.
[2] Han Yu*, et al.“Photocatalytic Dissolution of Precious Metals by TiO2 through Photogenerated Free Radicals” Angew. Chem. Int. Ed. 2022, 61, 50, e202213640.
[3] Han Yu*, et al.“Chemically Bonded Dot-on-Plate Z-Scheme Junction with Strong Interal Electric Field for Superior Upgrading Photo-oxidation of Aromatic Alcohols”Angew. Chem. Int. Ed. 2022, doi.org /10.1002/ anie. 202203519.
[4] Han Yu*, et al. “Synergistic Polarization Engineering on Bulk and Surface for Boosting CO2Photoreduction” Angew. Chem. Int. Ed. 2021,60, 18303-18308.
[5] Han Yu*, et al. “Selective oxidation of anilines to azobenzenes and azoxybenzenes by a molecular Mo oxide catalyst” Angew. Chem. Int. Ed. 2021, 60,6382-6385.
[6] Han Yu*, et al. “Light-Induced Efficient Hydroxylation of Benzene to Phenol by Quinolinium and Polyoxovanadate-based Supramolecular Catalysts”Angew. Chem. Int. Ed. 2021,60, 13310-13316.
[7] Han Yu*, et al.“An Efficient Iron(III)-Catalyzed Aerobic Oxidation of Aldehydes in Water for the Green Preparation of Carboxylic Acids” Angew. Chem. Int. Ed. 2017, 56, 3867-3871.(SCI一區,IF= 15.336)
[8] Han Yu*, et al.“Additive-Mediated Selective Oxidation of Alcohols to Esters via Synergistic Effect Using Single Cation Cobalt Catalyst Stabilized with Inorganic Ligand” Research,2020,doi.org /10.34133/2020/3875920
[9] Han Yu*, et al.“Selective iron-catalyzed aerobic oxidation of alcohols in water to carboxylic acids mediated by additives” Green Chem. 2022, 24, 6511-6516.
[10] Han Yu*, et al.“Oxidative carbon-carbon bond cleavage of 1,2-diols to carboxylic acids/ketones by an inorganic-ligand supported iron catalyst” Green Chem. 2021, 23, 9140-9146.
[11] Han Yu*, et al.“Oxidative esterification of alcohols by a single-side organically decorated Anderson-type chrome-based catalyst” Green Chem. 2021, 23, 2652-2657.
[12] Han Yu*, et al.“Transformation of Arylboronic Acids with Sodium Thiosulfate into Organodisulfides Catalyzed by Recyclable Polyoxometalate-based Green Cr(III) Catalyst” Green Chem.2021,23, 6059-6064.
[13] Han Yu*, et al.“An Efficient and Green Way for the N-Formylation of Amines by Inorganic-ligand Supported Iron Catalysis” Green Chem.2020,22, 737-741.
[14] Han Yu*, et al.“Highly Efficient Oxidation of Alcohols to Carboxylic Acids Using Polyoxometalate-supported Chromium(III) Catalyst and CO2” Green Chem.2020, 22, 3150-3154.
[15] Han Yu*, et al.“Aldehydes as potential acylating reagents for oxidative esterification by inorganic ligand supported iron catalysis” Green Chem.,2019, 21, 4550-4554.
6. 代表性授權專利:
[1] 餘焓;但德敏;吳志康,《一種1,5-萘二異氰酸酯的制備方法》,ZL201910469665.X
[2] 餘焓;但德敏;吳志康,《一種二甲基聯苯二異氰酸酯的制備方法》,ZL201910469697.X
[3] 餘焓;但德敏;吳志康,《一種4,4’-二環己基甲烷二異氰酸酯的制備方法》,ZL201910469044.1
[4] 餘焓;但德敏;吳志康,《一種甲苯二異氰酸酯的制備方法》,ZL201910469661.1
[5] 餘焓;但德敏;吳志康,《一種4,4’-二苯基甲烷二異氰酸酯的制備方法》,ZL201910469663.0
[6] 餘焓;但德敏;吳志康,《一種異佛爾酮二異氰酸酯的制備方法》,ZL201910469696.5
[7] 餘焓;程穎;胡敬;龍韬;常亞林,《7-喹啉酸配位的金屬催化劑及複合物的制備方法及應用》,ZL202310730944.3
[8] 餘焓;程穎;胡敬;龍韬;常亞林,《一種羟基喹啉配位的催化劑及複合物的制備方法及應用》,ZL202310730952.8
[9] 餘焓;程穎;胡敬;張可;龍韬;常亞林,《6-喹啉酸配位的金屬催化劑及複合物的制備方法及應用》,ZL202310730954.7
[10] 餘焓;劉秦;程穎;胡敬;龍韬,《一種高純度間甲基苯甲酸的制備系統及方法》,ZL202311140916.2