1. 個人簡介:
劉國華 博士,教授,有機化學專業碩士生導師;中國科學院化學研究所博士,荷蘭格羅甯根大學化學系博士後;現為上海師範大學bevictor伟德官网副院長,有機化學碩士點負責人;資源化學教育部聯合合作實驗室副主任;擔任上海市化學化工學會有機化學專業委員會理事,國際期刊Scientific Reports編委和上海市師範大學學報自然科學版編委。
郵箱:ghliu@shnu.edu.cn
2. 主要研究方向:
[1] 負載型催化劑的制備。
[2] 不對稱催化。
[3] 金屬有機化學。
3. 代表性科研項目:
[1] 催化活性點分離的雙功能負載型催化劑的構建和串聯不對稱反應研究,國家自然科學基金(面上項目),2017-2020。
[2] 手性功能化的有機/無機雜化納米材料制備及其合成反應評價,上海市科學技術委員會科研項目,2012-2015。
[3]介孔結構的矽基載體和限域效應對不對稱氫化反應影響,上海市教育委員會重點科研項目,2012-2014。
[4]手性雙功能介孔功能材料與金屬配位方式的探讨及不對稱氫化反應研究,上海市科學技術委員會基礎研重點項目,2010-2013。
[5] 手性雙功能介孔功能材料與金屬配位方式的探讨及不對稱氫化反應研究,上海市科學技術委員會基礎研究重大項目子項目,2010-2013。
4. 代表性論文:
[1]Liang Wu, Ronghua Jin, Liang Li, Xiaoying Hu, Tanyu Cheng, and Guohua Liu,* A Michael Addition−Asymmetric Transfer Hydrogenation One-Pot Enantioselective Tandem Process for Syntheses of Chiral γ Secondary Amino Alcohols, Org. Lett.2017, 19), 3047–3050. (Highlighted in Synfacts 2017, 13, 0904).
[2]Dongsong Zheng, Qiankun Zhao, Xiaoying Hu, Tanyu Cheng, Guohua Liu* and Wei Wang* A dynamic kinetic asymmetric transfer hydrogenation–cyclization tandem reaction: an easy access to chiral 3,4-dihydro-2H-pyran-carbonitriles, Chem. Commun. 2017, 53, 6113-6116. (Highlighted in Synfacts 2017, 13(09), 0918).
[3]Xuelin Xia, Jingjing Meng, Hanxin Wu, Tanyu Cheng and Guohua Liu*, Integration of multiple active sites on large-pore mesoporous silica for enantioselective tandem reactions, Chem. Commun. 2017, 53, 1638—1641.
[4]Jianyou Xu, Tanyu Cheng, Kun Zhang, Ziyun Wang and Guohua Liu*, Enantioselective tandem reaction over a site-isolated bifunctional catalyst, Chem. Commun. 2016, 52, 6005—6008.
[5]Lingyu Kong,Junwei Zhao, Tanyu Cheng, Jingrong Lin, and Guohua Liu,* A Polymer-Coated Rhodium/Diamine-Functionalized Silica for Controllable Reaction Switching in Enantioselective Tandem Reduction-Lactonization of Ethyl 2-Acylarylcarboxylates, ACS Catal.2016, 6, 2244-2249.
[6]Kun Zhang, Juzeng An, Yanchao Su, Jueyu Zhang, Ziyun Wang, Tanyu Cheng, Guohua Liu*, Amphiphilic Hyperbranched Polyethoxysiloxane: A Self-Templating Assembled Platform to Fabricate Functionalized Mesostructured Silicas for Aqueous Enantioselective Reactions, ACS Catal. 2016, 6, 6229–6235.
[7]Feng Zhou, Xiaoying Hu, Ming Gao, Tanyu Cheng*,Guohua Liu*, An Imidazolium-Modified Chiral Rhodium/diamine-Functionalized Periodic Mesoporous Organosilica for Asymmetric Transfer Hydrogenation of a–Haloketones and Benzils in Aqueous Medium, Green Chem. 2016, 18, 5651-5657.
[8]Xuelin Xia, Meng Wu, Ronghua Jin, Tanyu Cheng and Guohua Liu,* One-pot Relay Reduction-Isomerization of ß-Trifluoromethylated-a,ß-Unsaturated Ketones to chiral ß-Trifluoromethylated Saturated Ketones Over Combined Catalysts in Aqueous Medium, Green Chem.2015, 17, 3916 – 3922.
[9]Dacheng Zhang Tanyu Cheng Guohua Liu*, An imidazolium-based organopalladium-functionalized organic–inorganic hybrid silica promotes one-pot tandem Suzuki cross coupling–reduction of haloacetophenones and arylboronic acids, Applied Catalysis B: Environmental, 2015, 174–175, 344–349.
[10]Tanyu Cheng, Qiankun Zhao, Dacheng Zhang and Guohua Liu*, Transition-metal-functionalized ordered mesoporous silicas: an overview of sustainable chiral catalysts for enantioselective transformations, Green Chem. 2015, 17, 2100 (invited review paper).
5. 代表性授權專利:
[1]劉國華,徐建友,熊錫,吳亮,金榮華,程探宇;一種蛋殼結構的钯钌雙金屬功能化的介孔納米催化劑及其制備方法, 專利号:ZL 201510345863.7.
[2]劉國華,張大誠,王凱雯,呂雯雯,顧坤鵬,程探宇;一種Ru-Pd雙金屬負載型手性催化劑及其制備工藝,專利号:ZL 201410174583.X。
[3]劉國華,張大誠,徐建友,趙乾坤,吳猛,王金玉;一種具有相轉移催化性能的咪唑鎓鹽型卡賓钯催化劑及其制備方法,專利号:ZL 201410081268.2。
[4]劉國華,高小雙,徐向明,金榮華,程探宇;一種有序介孔有機矽磁球Fe3O4@PMO材料的制備方法,專利号:ZL 201310176009.3 (授權日期:2016-05-13)。
[5]劉國華,鄧博心,肖偉, 程探宇; 一種咪唑功能化的兩親介孔有機矽材料的制備方法,專利号:ZL 201310285620.X.
更新于2017年11月